Non-Fiction Books:

Transactions of the American Institute of Chemical Engineers, 1912, Vol. 5 (Classic Reprint)

Click to share your rating 0 ratings (0.0/5.0 average) Thanks for your vote!

Format:

Paperback / softback
Unavailable
Sorry, this product is not currently available to order

Description

Excerpt from Transactions of the American Institute of Chemical Engineers, 1912, Vol. 5 If we first produce the pure crystalline phenol-alcohol, contain ing no excess Of phenol, for instance crystalline saligenin or oxybenzyl-alcohol, and if we heat it gently, it will simply dehydrate and be transformed in a fusible mass which on cooling, solidifies to a resinous product - a fusible saliretin resin. The latter, submitted to the further action of heat, polymerizes and becomes an infusible, insoluble saliretin. This polymerization is facilitated, by the pres ence of small amounts of catalyzers, for instance, hydrochloric acid. The presence of an excess of phenol retards polymerization; hence the infusibility induced by polymerization will be retarded, and this, until some way or another the excess Of phenol has been expelled. The infusible polymerized saliretin obtained by heating phenol-alcohols containing no free phenol, or by heating fusible saliretin containing no free phenol, is insoluble in alcohol, but swells in acetone; it softens decidedly on heating, although it is no longer fusible. Longer heating does not harden it further, nor make it more resistive. It is harder, stronger, and more resistant to physical and chemical agents than the fusible saliretin from which it is derived; in this respect, it surpasses even more the soluble fusible resins described by Blumer, delaire, Baekeland, and called phenol resin by Aylesworth. But even after polymerization or hardening has been carried as far as possible, it is considerably less hard and less strong and less resistant to physical and chemical agents than the polymerization products resulting from the reaction of phenol on a sufficiently large proportion of formaldehyde or equivalent substances. In order to obtain the latter polymerization products of maxi mum strength. Hardness, and maximum resistivity, an adequately larger amount of methylen group must be introduced before or dur ing the act of polymerization. The introduction of this methylen group may be accomplished by at least three distinct methods. About the Publisher Forgotten Books publishes hundreds of thousands of rare and classic books. Find more at www.forgottenbooks.com This book is a reproduction of an important historical work. Forgotten Books uses state-of-the-art technology to digitally reconstruct the work, preserving the original format whilst repairing imperfections present in the aged copy. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in our edition. We do, however, repair the vast majority of imperfections successfully; any imperfections that remain are intentionally left to preserve the state of such historical works.
Release date Australia
March 11th, 2018
Audience
  • General (US: Trade)
Country of Publication
United Kingdom
Illustrations
115 Illustrations; Illustrations, black and white
Imprint
Forgotten Books
Pages
308
Publisher
Forgotten Books
Dimensions
152x229x17
ISBN-13
9781334185595
Product ID
26253219

Customer reviews

Nobody has reviewed this product yet. You could be the first!

Write a Review

Marketplace listings

There are no Marketplace listings available for this product currently.
Already own it? Create a free listing and pay just 9% commission when it sells!

Sell Yours Here

Help & options

Filed under...