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Molecular Conformation and Organic Photochemistry by Rasmus Y. Brogaard
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Molecular Conformation and Organic Photochemistry

Time-resolved Photoionization Studies
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Description

Rasmus Brogaard's thesis digs into the fundamental issue of how the shape of a molecule relates to its photochemical reactivity. This relation is drastically different from that of ground-state chemistry, since lifetimes of excited states are often comparable to or even shorter than the time scales of conformational changes. Combining theoretical and experimental efforts in femto-second time-resolved photoionization Rasmus Brogaard finds that a requirement for an efficient photochemical reaction is the prearrangement of the constituents in a reactive conformation. Furthermore, he is able to show that by exploiting a strong ionic interaction between two chromophores, a coherent molecular motion can be induced and probed in real-time. This way of using bichromophoric interactions provides a promising strategy for future research on conformational dynamics.
Release date Australia
June 11th, 2014
Audience
  • Professional & Vocational
Illustrations
XVI, 124 p.
Pages
124
Dimensions
155x235x8
ISBN-13
9783642426742
Product ID
22546924

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